Preheat the oven to 180°C / 160°C fan assisted / gas mark 4 / 350°F and line and grease 3 x 20cm (8 inch) round cake tins.
Place the sugar and butter in a large mixing bowl or bowl of a stand mixer and beat together for 2-3 minutes until pale, light and fluffy.
Add the eggs one at a time, continuing to mix on a low speed.
Add the vanilla extract, lemon zest and thyme leaves and mix in.
Sift the flour, baking powder, bicarbonate of soda and salt together in a large separate bowl.
Add the flour alternately with the sour cream, adding the flour in three additions and the sour cream in two (begin and end with the flour), scrape down the sides of the bowls as needed and mix until just combined.
Rest for 30 minutes to allow the gluten-free flours to settle and soften.
Pour the batter equally across the cake tins (about 375g per tin) and bake for 20 minutes until an inserted cocktail stick comes out clean.
Once the cakes have been removed from the oven, and taken carefully out of their tins, brush the limoncello over the top of the sponges using a pastry brush then leave to cool.