Pre-heat the oven to 180°C / 160°C fan assisted / gas mark 4 / 350°F and line and grease 2 x round 20cm (8 inch) cake tins.
Rub the orange zest into the sugar using your fingertips in a large mixing bowl or the bowl of a stand mixer.
Add the butter and mix with the sugar and butter until pale, light and fluffy, about 2-3 minutes, scraping down the sides every so often.
Add the eggs one at a time, beating on a low speed, until well incorporated.
Whisk together the gluten-free flour, poppy seeds, baking powder and salt in a large mixing bowl until completely combined.
Add the flour mix alternately with the sour cream, adding the flour in three additions and the sour cream in two (begin and end with the flour), scrape down the sides of the bowls as needed and mix until just combined.
Divide the cake batter between the two prepared cake tins and bake for 30 minutes or until an inserted cocktail stick comes out clean and the sponges are just starting to pull away from the sides.
Allow the sponges to rest for 5 minutes in their tins then carefully remove onto wire racks and allow to cool completely before assembling the cake.